Chapter 3: Water And The Fitness Of The Environment

24 July 2022
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polar molecule
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a molecule in which the two ends have opposite charges
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cohesion
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hydrogen bonding holds a substance together
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adhesion
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clinging of one substance to another
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surface tension
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measure of how difficult it is to stretch or break the surface of a liquid
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kinetic energy
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energy of motion
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heat
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measure of the matter's total kinetic energy
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temperature
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measure of heat intensity that represents the average kinetic energy of the molecules
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Celsius scale
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using celsius to indicate temperature
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calorie
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amount of heat it takes to raise the temperature of 1g of water by 1'C.
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kilocalorie
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amount of heat it takes to raise the temperature of 1kg of water by 1˚C.
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specific heat
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amount of heat that must be absorbed or lost for 1g of that substance to change its temperature by 1˚C.
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vaporization
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change from a liquid to a gas
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heat of vaporization
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quantity of heat a liquid must absorb for 1g of it to be converted from the liquid to the gas state
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evaporative cooling
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as a liquid evaporates, the surface that remains cools down
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solution
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liquid that is a completely homogeneous mixture of two or more substances
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solvent
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dissolving agent of a solution
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solute
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substance that is dissolved in a solution
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aqueous solution
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solution in which water is the solvent
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hydration shell
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sphere of water molecules around each dissolved ion
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hydrophilic
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any substance that has an affinity for water
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colloid
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stable suspension of fine particles in a liquid
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hydrophobic
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any substance that repels water
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molecular mass
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the sum of the masses of all the atoms in a molecule
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mole
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unit of measurement that represents 6.02 x 10²³
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molarity
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number of moles of solute per liter of solution
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hydrogen ion
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single proton
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hydroxide ion
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water molecule that lost a proton
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hydronium ion
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a water molecule with an extra proton
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acid
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substance that increases the hydrogen ion concentration of a solution
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base
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substance that reduces the hydrogen ion concentration of a solution
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pH
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a measure of hydrogen ion concentration in a solution based on a scale 1 to 14
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buffer
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substances that minimize changes in the concentrations of H⁺ and OH⁻ in a solution
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acid precipitation
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rain, snow, or fog with a pH lower than pH 5.2
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Joule
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a unit of energy: one joule= 0.239 cal, and one cal= 4.184J.
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Each water molecule is joined to _____ other water molecules by ____ bonds.
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four ... hydrogen
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What name is given to this molecule? HO3+
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Hydronium ion: A water molecule that gains a hydrogen becomes a hydronium ion.
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What name is given to this molecule? HO-
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Hydroxide ion: A water molecule that loses a hydrogen ion is referred to as a hydroxide ion.
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Which of these is the correct equation for the dissociation of water?
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H2O + H2O <==> H3O+ + OH-
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What is the charge on a hydronium ion?
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+1
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What is the charge on a hydroxide ion?
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-1 A hydroxide ion is formed when a water molecule loses a hydrogen ion.
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About _____ molecules in a glass of water are dissociated.
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1 in 500,000,000 (one in half a billion)
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In a neutral solution the concentration of _____. (hydrogen ions vs. hydroxide ions)
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The correct answer: hydrogen ions is equal to the concentration of hydroxide ions. This describes a basic solution.
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An acid is...
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a substance that increases the hydrogen ion concentration of a solution. ex when HCl is added to water, it dissociates into H+ and Cl-
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a base is...
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a substance that reduces the hydrogen ion concentration, sometimes by directly accepting H+ ions. ex ammonia (NH3) acts as a base when the unshared electron pair in nitrogen's valence shell attracts an H+ ion, resulting in an ammonium ion (NH4+). Other bases reduce the H+ concentration indirectly by dissociating to form hydroxide ions, which combine with hydrogen ions and form water. ex NaOH becomes Na+ and OH-.
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strong acids+bases are
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compounds that dissociate completely when mixed with water ex HCl (acid) and NaOH (base)
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weak acids+bases are
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compounds that reversibly release and accept back hydrogen ions. ex carbonic acid (H2CO3) can dissociate to become HCO3- and H+, but these can combine back again. Also NH3 and H+ can become NH4+ or break apart again.
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Assume that acid rain has lowered the pH of a particular lake to pH 4.0. What is the hydroxyl ion concentration of this lake?
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1 x 10^-10 mol of hydroxyl ion per liter of lake water
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In any aqueous solution at 25˚C, the product of the H+ and OH- concentrations is constant at _______ this can be written as ______
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10^-14. This can be written as [H+][OH-] = 10^-14. the brackets indicate molar concentration.
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In any neutral solution at room temperature 25˚C, [H+]=_______ and [OH-]=________
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[H+]=10^-7 and [OH-]=10^-7.
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If [H+]= 10^-11 then [OH-] will equal
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10^-3
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water's high specific heat is mainly a consequence of the...
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absorption and release of heat when hydrogen bonds break and form.
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Carbon dioxide (CO2) is readily soluble in water, according to the equation CO2 + H2O <--> H2CO3. Carbonic acid (H2CO3) is a weak acid. Respiring cells release CO2. What prediction can we make about the pH of blood as that blood first comes in contact with respiring cells?
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Blood pH will decrease slightly because CO2 is acidic, so it has a higher concentration of H+ ions which will lead to a decreased pH in the blood as these ions bind to the OH-.