BIOL Ch 4

25 July 2022
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Organic chemistry is currently defined as
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the study of carbon compounds.
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MAKE CONNECTIONS Which chemical group is most likely to be responsible for an organic molecule behaving as a base (see Concept 3.3, p. 53 in your textbook)?
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amino
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Which of the following hydrocarbons has a double bond in its carbon skeleton?
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C2H4
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Which action could produce a carbonyl group?
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the replacement of the -OH of a carboxyl group with hydrogen
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Which statement about isomers is correct?
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Enantiomers differ in biological activity.
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Which statement about a methyl functional group is correct?
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A methyl group consists of a carbon bonded to three hydrogen atoms.
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Identify the functional groups.
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Amino and carboxyl are functional groups.
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How do isomers differ from one another?
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Isomers differ in the arrangement or bonding of atoms.
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The element present in all organic molecules is
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carbon.
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Differences among organisms are caused by
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differences in the types and relative amounts of organic molecules synthesized by each organism.
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Most organic compounds contain carbon and
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hydrogen
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The experiments of Wöhler, Kolbe, Miller, and other chemists invalidated the concept of vitalism by demonstrating that
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organic molecules could be produced apart from living organisms using inorganic materials
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Vitalism gave way to mechanism, the view that
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physical and chemical laws govern living systems
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The complexity and variety of organic molecules is due to
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the chemical versatility of carbon atoms.
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The experimental approach taken in current biological investigations presumes that The experimental approach taken in current biological investigations presumes that The experimental approach taken in current biological investigations presumes that
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living organisms can be understood in terms of the same physical and chemical laws that can be used to explain all natural phenomena.
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Which of the following people was the first to synthesize an organic compound, urea, from inorganic starting materials?
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Friedrich Wohler
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Hermann Kolbe's synthesis of an organic compound, acetic acid, from inorganic substances that had been prepared directly from pure elements was a significant milestone for what reason?
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It proved that organic compounds could be synthesized from inorganic compounds and disproved the concept of vitalism.
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When Stanley Miller applied heat and electrical sparks to a mixture of simple inorganic compounds such as methane, hydrogen gas, ammonia, and water vapor, what compounds were produced?
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both simple organic compounds and more complex organic compounds such as amino acids and hydrocarbons
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Stanley Miller's 1953 experiments supported the hypothesis that
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organic molecules can be synthesized abiotically under conditions that may have existed on early Earth.
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Stanley Miller's 1953 experiments assumed that early Earth's atmosphere contained
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ammonia, methane, hydrogen gas, and water vapor.
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L-dopa is used to treat
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Parkinson's disease
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Enantiomers are molecules that
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are mirror images
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Geometric isomers are molecules that
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differ in the arrangement of their atoms about a double bond
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A carbon atom is most likely to form what kind of bond(s) with other atoms?
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covalent
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Which of the following statements best describes the carbon atoms present in a seed-eating bird?
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They were incorporated into organic molecules by plants, they were processed into sugars through photosynthesis, and they are ultimately derived from carbon dioxide.
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Which of the following statements best describes the carbon atoms present in a seed-eating bird?
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The carbon atoms ultimately came from carbon dioxide incorporated into sugars through photosynthesis.
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Why are hydrocarbons insoluble in water?
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The majority of their bonds are nonpolar covalent carbon-to-hydrogen linkages.
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The large diversity of shapes of biological molecules is possible because of the extensive presence of _____ in the molecules.
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carbon
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Which of the following is a hydrocarbon?
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C3H8
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Molecules that have the same chemical formula (same numbers of each atom) but different three-dimensional shapes are called
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isomers
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Which of the following best describes cis-trans isomers?
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They differ in their spatial arrangement around inflexible double bonds.
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How many electron pairs does carbon share in order to complete its valence shell?
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4
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How many structural isomers are possible for a substance having the molecular formula C4H10?
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2
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Which of the following statements correctly describes cis-trans isomers?
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They have variations in arrangement around a double bond.
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Research indicates that ibuprofen, a drug used to relieve inflammation and pain, is a mixture of two enantiomers; that is, molecules
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are mirror images of one another.
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What determines whether a carbon atom's covalent bonds to other atoms are in a tetrahedral configuration or a planar configuration?
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the presence or absence of double bonds between the carbon atom and other
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Compared to a hydrocarbon chain where all the carbon atoms are linked by single bonds, a hydrocarbon chain with the same number of carbon atoms, but with one or more double bonds, will
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be more constrained in structure.
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Organic molecules with only hydrogens and five carbon atoms can have different structures in all of the following ways except
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by forming enantiomers
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Thalidomide and L-dopa, shown below, are examples of pharmaceutical drugs that occur as enantiomers, or molecules that
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are mirror images of one another.
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Citric acid makes lemons taste sour. Which of the following is a functional group that would cause a molecule such as citric acid to be acidic?
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carboxyl
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Variations in the reactive properties of different organic molecules are most closely associated with
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the presence or absence of functional groups
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What functional group is commonly used in cells to transfer energy from one organic molecule to another?
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phosphate
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A compound contains hydroxyl groups as its predominant functional group. Which of the following statements is true concerning this compound?
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It should dissolve in water.
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Which two functional groups are always found in amino acids?
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carboxyl and amino
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Amino acids are acids because they always possess which functional group?
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carboxyl
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Testosterone and estradiol are male and female sex hormones, respectively, in many vertebrates. In what way(s) do these molecules differ from each other?
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Testosterone and estradiol have different functional groups attached to the same carbon skeleton.
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A chemist wishes to make an organic molecule less acidic. Which of the following functional groups should be added to the molecule in order to do so?
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amino
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Which chemical group can act as an acid?
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carboxyl
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A carbon skeleton is covalently bonded to both an amino group and a carboxyl group. When placed in water it
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would function as both an acid and a base